If you are a kohen you can’t say it when you’re duchening, but if you’re a kohen your children are too and being blessed by a kohen is the oldest “segula” around and the only one sanctioned by the Torah. You do not have to wait until a time when the tzibbur duchens to get this bracha. Not sure if they make the bracha on blessing you (??? ????? ??????? ?? ?????) when it’s not an “official” duchening. Ask your rav.
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