Dear Spark,
You have two strong feelings that coincide. It seems that you would be just about the only one wearing a black hat. The impact of wearing the only black hat, will be more noticeable (And hence more of a statement.) than wearing one for davening. If there are times that you unable to join a minyan, you can wear one then. If you always daven with a minyan, you can still get one and wear it for Bircas Hamozon. Then you could decide, or ask your Rabbi what to do next.
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