I may be mistaken but I seem to remember that the Chasam Sofer writes that a woman who remarries automatically is cutting her connection to her first husband (someone correct me if i’m wrong).
Based on that I’d assume that she remains with her second husband, but on the other hand, there are those that write that the zivug as they call it “bashert” (arba’im yom etc), is the first one, and the “zivug kasha kekriyat yam suf” goes on a zivug sheni, which is why it is so hard, because there is no kodem yetziyat havlad considered, rather it is reliant on the zechutim of the person, so in that case it would seem that the first one is the one that the woman would go back to.
As others wrote above, it is a very heavily debated topic in the Poskim, and the answer for now is probably- even though not so exciting, but – teiku.
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